Abstract
The kinetics of the decomposition of acetylcyclohexylsulfonyl peroxide (ACSP) in CCl4, benzene, toluene, ethylbenzene, cumene, acetonitrile, ethanol, and 2-propanol in an atmosphere of O2 were studied at 40–70 °C. The rate constants (k 0) and activation parameters of the monomolecular decomposition of ACSP were determined. A linear dependence between logA 0 and activation energyE 0 (compensation effect) was established. The dependence ofk 0 on the nature of a solvent is described by the four-parameter Koppel-Palm equation.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 935–937, May 1997.
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Zaripov, R.N., Safiullin, R.L., Yaubasarova, E.I. et al. Effect of the solvent on the kinetics of thermal decomposition of acetylcyclohexylsulfonyl peroxide. Russ Chem Bull 46, 895–897 (1997). https://doi.org/10.1007/BF02496114
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DOI: https://doi.org/10.1007/BF02496114