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Induced decomposition of di(tert-butyl)trioxide

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Thermal decomposition of di(tert-butyl)trioxide (ButOOOBut) in a wide range of concentrations was studied by visible and IR chemiluminescence. Induced decomposition of ButOOOBut caused by its reaction with the peroxy radicals formed in the solvent (CH2Cl2) was found and investigated.

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Authors and Affiliations

  1. Bashkortostan State University, 32 ul. Frunze, 450074, Ufa, Russian Federation

    S. L. Khursan

  2. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    A. F. Khalizov & V. V. Shereshovets

Authors
  1. S. L. Khursan
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  2. A. F. Khalizov
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  3. V. V. Shereshovets
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 924–927, May, 1997.

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Khursan, S.L., Khalizov, A.F. & Shereshovets, V.V. Induced decomposition of di(tert-butyl)trioxide. Russ Chem Bull 46, 884–887 (1997). https://doi.org/10.1007/BF02496111

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  • DOI: https://doi.org/10.1007/BF02496111

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