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Synthesis and spectral properties of titanium(iv) polynuclear hydroxo complexes stabilized in solution by the [PW11O39]7− heteropolyanion

  • General and Inorganic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Unsaturated heteropolyanions (HPA) [PW11O39]7− stabilize TiIV hydroxo complexes in aqueous solutions (Ti: PW11 [PW11O39]7−⪯12, pH 1–3). Spectral studies (optical,17O and31P NMR, and IR spectra) and studies by the differential dissolution method demonstrated that TiIV hydroxo complexes are stabilized through interactions of polynuclear TiIV hydroxo cations with heteropolyanions [PW11TiO40 5− formed. Depending on the reaction conditions, hydroxo cations Ti n−1O x H y m+ either add to oxygen atoms of the W−O−Ti bridges of the heteropolyanions to form the complex [PW11TiO40·Ti n−1O x H y ]k− (at [HPA]=0.01 mol L−1) or interact with TiIV of the heteropolyanions through the terminal o atom to give the polynuclear complexes [PW11O39Ti−O−Ti n−1O x H y ]q− (at [HPA]=0.2 mol L−1). When the complexes of the first type were treated with H2O2, TiIV ions added peroxo groups.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    L. G. Detsuheva, M. A. Fedotov, L. I. Kuznetsova, A. A. Vlasov & V. A. Likholobov

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  1. L. G. Detsuheva
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  2. M. A. Fedotov
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  3. L. I. Kuznetsova
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  4. A. A. Vlasov
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  5. V. A. Likholobov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 914–920, May, 1997.

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Detsuheva, L.G., Fedotov, M.A., Kuznetsova, L.I. et al. Synthesis and spectral properties of titanium(iv) polynuclear hydroxo complexes stabilized in solution by the [PW11O39]7− heteropolyanion. Russ Chem Bull 46, 874–880 (1997). https://doi.org/10.1007/BF02496109

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  • DOI: https://doi.org/10.1007/BF02496109

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