Abstract
Phenyltetrafluorotelluromethoxide fluorinates olefins to form 1,2-difluorides. The reaction with styrene afforded 1-fluoro-4-phenyl-1,2-dihydronaphthalene as the main product.
References
S. A. Lermontov, S. I. Zavorin, I. V. Bahtin, N. S. Zefirov, and P. J. Stang,Phosphorus, Sulfur, and Silicon, 1995,102, 283; S. A. Lermontov, I. V. Bahtin, S. I. Zavorin, N. S. Zefirov, and P. J. Stang,J. Fluorine Chem., 1998, in press.
A. F. Janzen, K. Alam, and B. J. Blackburn,J. Fluorine Chem., 1989,42, 173.
R. Hoffman, J. M. Howell, and E. L. Muetterties,J. Am. Chem. Soc., 1972,94, 3047; J. M. Howell,J. Am. Chem. Soc., 1977,99, 7447; W. Kutzelnigg and J. Wasilewski,J. Am. Chem. Soc., 1982,104, 953.
T. Yamauchi, K. Hattory, S. Mizutaki, K. Tamaki, and S. Uemura,Bull. Chem. Soc. Jpn., 1986,59, 3617.
N. Petragnani and J. V. Comasseto,Synthesis, 1991, 793.
M. Zupan and A. Pollak,J. Org. Chem., 1976,41, 4002.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 742–744, April, 1998
Rights and permissions
About this article
Cite this article
Lermontov, S.A., Bahtin, I.V. Phenyltetrafluorotelluromethoxide — a new fluorinating reagent for olefins. Russ Chem Bull 47, 722–723 (1998). https://doi.org/10.1007/BF02495986
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02495986