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Synthesis and properties of 7,7-dichloro-3,4-benzobicyclo[4.1.0]heptane, its tricarbonylchromium complexes, and isomeric 7-chloro-3,4-benzobicyclo[4.1.0]heptanes

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reaction of Cr(CO)6 with 7,7-dichloro-3,4-benzobicyclo[4.1.0]heptane gave the correspondingexo- andendo-chromium tricarbonyl complexes in a ratio of 4.5:1. The structures of the resulting compounds were established by NMR spectroscopy, mass spectrometry, and X-ray structural analysis. Reduction of dichlorobenzobicycloheptane and its chromium tricarbonyl complexes with LiAlH4 affordedexo- andendo-7-chloro-3,4-benzobicyclo[4.1.0]heptanes in a 3.5:1 ratio.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    A. V. Vorogushin, M. D. Reshetova, N. G. Akhmedov & Yu. A. Ustynyuk

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    I. L. Eremenko & S. E. Nefedov

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    A. I. Zinin

Authors
  1. A. V. Vorogushin
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  2. M. D. Reshetova
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  3. N. G. Akhmedov
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  4. Yu. A. Ustynyuk
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  5. I. L. Eremenko
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  6. S. E. Nefedov
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  7. A. I. Zinin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 720–724, April, 1998.

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Vorogushin, A.V., Reshetova, M.D., Akhmedov, N.G. et al. Synthesis and properties of 7,7-dichloro-3,4-benzobicyclo[4.1.0]heptane, its tricarbonylchromium complexes, and isomeric 7-chloro-3,4-benzobicyclo[4.1.0]heptanes. Russ Chem Bull 47, 699–703 (1998). https://doi.org/10.1007/BF02495983

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  • DOI: https://doi.org/10.1007/BF02495983

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