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Synthesis of 2-arylhydrazones of aliphatic fluorine-containing 1,2,3-tricarbonyl compounds and their reactions with dinucleophiles

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

New fluorinated 2-arylhydrazones of 1,2,3-tricarbonyl compounds were obtained by coupling fluorine-containing 3-oxo esters, 1,3-diketones, and their copper chelates with aryldiazonium chlorides. Reactions of these arylhydrazones with hydrazine hydrate, phenylhydrazine, thiosemicarbazide, and hydroxylamine gave the corresponding pyrazole and isoxazole derivatives.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation

    O. G. Kuzueva, Ya. V. Burgart & V. I. Saloutin

Authors
  1. O. G. Kuzueva
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  2. Ya. V. Burgart
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  3. V. I. Saloutin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 695–700, April, 1998.

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Kuzueva, O.G., Burgart, Y.V. & Saloutin, V.I. Synthesis of 2-arylhydrazones of aliphatic fluorine-containing 1,2,3-tricarbonyl compounds and their reactions with dinucleophiles. Russ Chem Bull 47, 673–678 (1998). https://doi.org/10.1007/BF02495977

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  • DOI: https://doi.org/10.1007/BF02495977

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