Abstract
Di(tert-butylperoxy)triphenylbismuth and the triphenylbismuth—tert-butyl hydroperoxide system react with aliphatic alcohols and cyclohexanol to give carbonyl compounds in high yields. The oxidation occurs as the radical dehydrogenation of alcohols; Bi derivatives serve as the sources of free radicals.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 681–684, April, 1998.
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Zinov'eva, T.I., Dolganova, N.V., Dodonov, V.A. et al. Di(tert-butylperoxy)triphenylbismuth and the triphenylbismuth—tert-butyl hydroperoxide system as efficient oxidants of alcohols. Russ Chem Bull 47, 659–662 (1998). https://doi.org/10.1007/BF02495973
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DOI: https://doi.org/10.1007/BF02495973