Abstract
The interaction of NO2 with sublimed films ofmeso-tetraphenylporphyrinatozinc was studied by IR and UV-VIS spectroscopy. The π-radical cation (ZnTPP)•+NO2 − containing an unpaired electron on HOMO of the A2u symmetry is formed at the first stage of the reaction. The second NO2 molecule attacks themeso-carbon atom to form zinc isoporphyrin with the covalently bound nitro group. The IR data indicate that the NO2 − anion is axially coordinated to the central metal atom, and the NO2 group is covalently bonded through the N atom.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 665–668, April, 1998.
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Kurtikyan, T.S., Stepanyan, T.G., Gasparyan, A.V. et al. Interaction of nitrogen dioxide with sublimed films ofmeso-tetraphenylporphyrinatozinc. Russ Chem Bull 47, 644–647 (1998). https://doi.org/10.1007/BF02495969
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DOI: https://doi.org/10.1007/BF02495969