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The volume of micropores and the Dubinin—Radushkevich equation

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The substantiation and the area of applicability of the Dubinin—Radushkevich equation for determination of the micropore volume in microporous systems from experimental data on adsorption isotherms were examined. It was shown that the micropore volumes found using the standard procedure are overestimated. A more accurate method for determining the mircopore volumes based on the pressure of filling of micropores was proposed.

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Authors and Affiliations

  1. State Scientific Center of the Russian Federation “L. Ya. Karpov Institute of Physical Chemistry, 10 ul. Vorontsovo Pole, 103064, Moscow, Russian Federation

    Yu. K. Tovbin

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  1. Yu. K. Tovbin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 659–664, April, 1998.

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Tovbin, Y.K. The volume of micropores and the Dubinin—Radushkevich equation. Russ Chem Bull 47, 637–643 (1998). https://doi.org/10.1007/BF02495968

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  • DOI: https://doi.org/10.1007/BF02495968

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