Skip to main content
SpringerLink
Log in

Kinetics of solid state reactions with a positive feedback between the reaction and fracture

1. A quantitative model for movement of fracture front

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A model describing the steady-state kinetics of thermal decomposition in the solid phase occurring with a decrease in the solid phase volume and accompanied by fracture in the reaction zone is suggested. The model is based on the concept of positive feedback between the reaction and fracture. The rate of the fracture front and the size of the product fragments formed were calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. V. Boldyrev,Usp. Khim., 1973,27, 116 [Russ. Chem. Res., 1973,27 (Engl. Transl.)].

    Google Scholar 

  2. V. V. Boldyrev, M. Bulens, and B. Delmon,The Control of the Reactivity of Solids, Elsevier, Amsterdam, 1979, 229 pp.

    Google Scholar 

  3. N. Z. Lyakhov, inProblemy sovremennoi fizicheskoi khimii [Problems of Modern Physical Chemistry], Ed. Ya. M. Kolotyrkin, Khimiya, Moscow, 1988, 221 (in Russian).

    Google Scholar 

  4. A. P. Chupakhin, A. A. Sidelnikov, and V. V. Boldyrev,Reactivity of Solids, 1987,3, 1.

    Article  CAS  Google Scholar 

  5. H. R. Oswald, J. R. Gunter, and E. J. Dubler,J. Solid State Chem., 1975,13, 330.

    Article  CAS  Google Scholar 

  6. J. C. Mutin and G. J. Watelle,J. Solid State Chem., 1979,28, 1.

    Article  CAS  Google Scholar 

  7. V. B. Okhotnikov, N. A. Simakova, and B. I. Kidyarov,React. Kinet. Catal. Lett., 1989,39, 345.

    Article  CAS  Google Scholar 

  8. A. A. Sidelnikov, R. P. Mitrofanova, and V. V. Boldyrev,Termochim. Acta., 1994,234, 269.

    Article  CAS  Google Scholar 

  9. B. I. Yakobson,Pis'ma v ZhETF [Letters to Zh. Experim. Theor. Phys.], 1989,49, 27 (in Russian).

    CAS  Google Scholar 

  10. Yu. Kovalenko and E. L. Goldberg,Solid State Ionics, 1990,42, 159.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Chemistry and Mineral Raw Material Processing, Siberian Branch of the Russian Academy of Sciences, 18 ul. Kutateladze, 630128, Novosibirsk, Russian Federation

    S. A. Chizhik & A. A. Sidel'nikov

Authors
  1. S. A. Chizhik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Sidel'nikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 626–631, April, 1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chizhik, S.A., Sidel'nikov, A.A. Kinetics of solid state reactions with a positive feedback between the reaction and fracture. Russ Chem Bull 47, 604–609 (1998). https://doi.org/10.1007/BF02495962

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02495962

Key words

Search

Navigation