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Interaction of rhenium hydride (η5-C5Me5)ReH(CO)(NO) with fluorinated alcoholswith fluorinated alcohols

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Abstract

The interaction between the fluorinated alcohols RFOH (RF=(CF3)2CH and (CF3)3C) and rhenium hydride (η5-C5Me5)ReH(CO)(NO) in hexane and liquid freon was studied in a wide temperature range by IR and1H NMR methods, respectively. The formation of hydrogen-bonded complexes of two types, ReH...HORF and NO...HORF, was established. The hydride signal in the1H NMR spectra at 96 K splits into two signals (at δ=−7.54 and −8.87) corresponding to the free ReH and the ReH...HO complex, respectively.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    E. S. Shubina, N. V. Belkova, A. V. Ionidis & L. M. Epshtein

  2. Research Institute for Medical Antibiotics and Enzymes, 41 prosp. Rizhsky, 198020, St-Petersburg, Russian Federation

    N. S. Golubev & S. N. Smirnov

  3. Institute für Organische Chemie, Freie Universität, 3 Takustr., 14195, Berlin

    P. Shakh-Mokhammedi

Authors
  1. E. S. Shubina
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  2. N. V. Belkova
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  3. A. V. Ionidis
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  4. N. S. Golubev
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  5. S. N. Smirnov
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  6. P. Shakh-Mokhammedi
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  7. L. M. Epshtein
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1405–1407, July, 1997.

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Shubina, E.S., Belkova, N.V., Ionidis, A.V. et al. Interaction of rhenium hydride (η5-C5Me5)ReH(CO)(NO) with fluorinated alcoholswith fluorinated alcohols. Russ Chem Bull 46, 1349–1351 (1997). https://doi.org/10.1007/BF02495941

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  • DOI: https://doi.org/10.1007/BF02495941

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