Russian Chemical Bulletin

, Volume 46, Issue 7, pp 1317–1320 | Cite as

Synthesis of clusters Fe2(CO)6(μ-XCH2CH=CH2)(μ3-X)Fe(CO)2Cp (X = Se, S; Cp = η5-C5H5)

  • S. N. Konchenko
  • V. A. Maksakov
  • I. Yu. Filippov
  • V. A. Varnek
Organometallic Chemistry

Abstract

The clusters Fe2(CO)6(μ-XCH2CH=CH2)(μ3-X)Fe(CO)2Cp (X = S, Se) were prepared by the successive treatment of the bi- and trimetallic complexes Fe2(CO)6(μ-Se2) and Fe3(CO)93-X) with allylmagnesium chloride and CpFe(CO)2I. The clusters obtained contain a noncoordinated C=C bond. The structure of the Se-containing cluster was suggested on the basis of comparison of its spectral data (IR,1H NMR, and Mössbauer spectra) with the spectra of the analogous S-containing complex, which was previously characterized by X-ray diffraction analysis.

Key words

carbonyl clusters cluster monomers iron sulfur selenium synthesis 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • S. N. Konchenko
    • 1
  • V. A. Maksakov
    • 1
  • I. Yu. Filippov
    • 1
  • V. A. Varnek
    • 1
  1. 1.Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirsk

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