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Oxidation of 2-dialkylaminomethyl-4,6-di-tert-butylphenols

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Oxidative transformations of 2-dialkylaminomethyl-4,6-di-tert-butylphenols depend on the nature of the oxidant, the character of the substituents at the nitrogen atom, and the medium. A mechanism of the oxidation of these compounds is suggested. The molecular structure of the compound obtained as a result of oxidative trimerization of 2-dimethylaminomethyl-4,6-di-tert-butylphenol was established by X-ray structural analysis.

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References

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Authors and Affiliations

  1. N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117997, Moscow, Russian Federation

    I. S. Belostotskaya, V. B. Vol'eva, N. L. Komissarova & V. V. Ershov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28. ul. Vavilova, 117393, Moscow, Russian Federation

    M. O. Dekaprilevich & V. N. Khrustalev

  3. Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    A. Yu. Karmilov

Authors
  1. I. S. Belostotskaya
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  2. V. B. Vol'eva
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  3. N. L. Komissarova
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  4. M. O. Dekaprilevich
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  5. V. N. Khrustalev
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  6. A. Yu. Karmilov
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  7. V. V. Ershov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1328–1335, July, 1997.

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Belostotskaya, I.S., Vol'eva, V.B., Komissarova, N.L. et al. Oxidation of 2-dialkylaminomethyl-4,6-di-tert-butylphenols. Russ Chem Bull 46, 1272–1280 (1997). https://doi.org/10.1007/BF02495927

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  • DOI: https://doi.org/10.1007/BF02495927

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