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Russian Chemical Bulletin

, Volume 46, Issue 7, pp 1199–1210 | Cite as

Homolytic addition of dithiols to alkynes: A new approach to the construction of dithiacyclanes and crown thioethers

  • E. I. Troyansky
  • D. V. Demchuk
  • G. I. Nikishin
Reviews

Abstract

A novel general approach to the construction of sulfur-containing heterocyclic compounds and crown thioethers based on one-pot “assembling” of their molecules from α,ω-dithiols and alkynesvia homolytic cycloaddition has been developed.

Key words

homolytic cycloaddition homolytic macrocyclization α,ω-dithiols alkynes dithiacyclanes crown thioethers 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • E. I. Troyansky
    • 1
  • D. V. Demchuk
    • 1
  • G. I. Nikishin
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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