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Synthesis of bis-cyclopentadienyl compounds with a 9,9-fluorenylidene bridge. Crystal and molecular structure of [μ-9,9-Flu(η5-Cp)2]ZrCl2

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

An efficient synthetic approach to 9,9-bis(cyclopentadienyl)fluorenes was developed. The two correspondingansa-zirconocenes were synthesized. The structure of one of these compounds was established by X-ray diffraction analysis.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    N. B. Ivchenko, P. V. Ivchenko, I. E. Nifant'ev & V. V. Bagrov

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    L. G. Kuz'mina

Authors
  1. N. B. Ivchenko
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  2. P. V. Ivchenko
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  3. I. E. Nifant'ev
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  4. V. V. Bagrov
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  5. L. G. Kuz'mina
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1290–1294, July, 2000.

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Ivchenko, N.B., Ivchenko, P.V., Nifant'ev, I.E. et al. Synthesis of bis-cyclopentadienyl compounds with a 9,9-fluorenylidene bridge. Crystal and molecular structure of [μ-9,9-Flu(η5-Cp)2]ZrCl2 . Russ Chem Bull 49, 1287–1291 (2000). https://doi.org/10.1007/BF02495776

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  • DOI: https://doi.org/10.1007/BF02495776

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