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Asymmetric nitrogen

82. Tröger base: Study of its complex with HgBr2 and its methiodide

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Reactions of the Tröger base (1) with HgBr2 and Mel proceed with the participation of only one N atom. According to the data of X-ray diffraction analysis, the complex [(±)-1]2·HgBr2 crystallizes in the achiral space groupP n . Unlike the complex [(+)-1]2·HgBr2, methiodide of (+)-1 in MeOH undergoes racemization at 20°C. The virtual spin-spin coupling constants4 J HH observed for the base (C 2 symmetry) are transformed into the “usual” constants in the case of the desymmetrized methiodide system.

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Authors and Affiliations

  1. Higher Chemical College of the Russian Academy of Sciences, 9 Miusskaya pl., 125820, Moscow, Russian Federation

    D. A. Lenev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    K. A. Lyssenko

  3. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    R. G. Kostyanovsky

Authors
  1. D. A. Lenev
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  2. K. A. Lyssenko
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  3. R. G. Kostyanovsky
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Additional information

For Part 81, see Ref. 1.

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1244–1247, July, 2000.

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Lenev, D.A., Lyssenko, K.A. & Kostyanovsky, R.G. Asymmetric nitrogen. Russ Chem Bull 49, 1241–1244 (2000). https://doi.org/10.1007/BF02495767

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