Russian Chemical Bulletin

, Volume 47, Issue 3, pp 441–446 | Cite as

Cubane derivatives

2. Synthesis and structures of some esters of 1,4-cubanedicarboxylic acid
  • L. T. Eremenko
  • L. B. Romanova
  • M. E. Ivanova
  • A. V. Shastin
  • I. L. Eremenko
  • S. E. Nefedov
Organic Chemistry
  • 48 Downloads

Abstract

New esters of 1,4-cubanedicarboxylic acid, 1,4-(ROCO)2C8H6 (R=Et (3a), Pr (3b), CMe3 (3c), C6H13 (3d), CH2CF3 (3e), or CH(CF3)2 (3f) were synthesized. The structures of esters3a, 3b, 3e, and3f were established by X-ray diffraction analysis. The cubane framework of compound3b is somewhat distorted, whereas the C−C bond lengths and bond angles in the other compounds remain virtually ideal.

Key words

1,4-cubanedicarboxylic acid esters X-ray diffraction analysis 

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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • L. T. Eremenko
    • 1
  • L. B. Romanova
    • 1
  • M. E. Ivanova
    • 1
  • A. V. Shastin
    • 1
  • I. L. Eremenko
    • 2
  • S. E. Nefedov
    • 2
  1. 1.Institute of Chemical PhysicsRussian Academy of SciencesChernogolovkaMoscow RegionRussian Federation
  2. 2.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation

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