Russian Chemical Bulletin

, Volume 47, Issue 8, pp 1585–1588 | Cite as

Reactions of chiral phosphoramidites with complexes Pd(COD)Cl2 and Pt(COD)Cl2

  • I. S. Mikhel
  • K. N. Gavrilov
  • A. I. Polosukhin
  • A. I. Rebrov
Organometallic Chemistry


Reactions of phosphoramidites based on (−)-ephedrine and [(1S)-endo]-(−)-borneol with the complexes M(COD)Cl2 (M is Pd or Pt, and COD is cycloocta-1,5-diene) were studied. The formation ofcis andtrans complexes of the general formulas MCl2L2 and M2Cl2(μ-Cl)2L2 was observed. The structures of the resulting compounds were established by31P,13C, and195Pt NMR and IR spectroscopy and by plasma desorption mass spectrometry.

Key words

phosphoramidites palladium complexes platinum complexes coordination 2-diethylamino-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidine dibornyl diethylphosphoramidite 


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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • I. S. Mikhel
    • 1
  • K. N. Gavrilov
    • 1
  • A. I. Polosukhin
    • 2
  • A. I. Rebrov
    • 3
  1. 1.S. A. Esenin Ryazan' State Pedagogical UniversityRyazan'Russian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.A. V. Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussian Federation

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