Russian Chemical Bulletin

, Volume 47, Issue 8, pp 1585–1588 | Cite as

Reactions of chiral phosphoramidites with complexes Pd(COD)Cl2 and Pt(COD)Cl2

  • I. S. Mikhel
  • K. N. Gavrilov
  • A. I. Polosukhin
  • A. I. Rebrov
Organometallic Chemistry

Abstract

Reactions of phosphoramidites based on (−)-ephedrine and [(1S)-endo]-(−)-borneol with the complexes M(COD)Cl2 (M is Pd or Pt, and COD is cycloocta-1,5-diene) were studied. The formation ofcis andtrans complexes of the general formulas MCl2L2 and M2Cl2(μ-Cl)2L2 was observed. The structures of the resulting compounds were established by31P,13C, and195Pt NMR and IR spectroscopy and by plasma desorption mass spectrometry.

Key words

phosphoramidites palladium complexes platinum complexes coordination 2-diethylamino-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidine dibornyl diethylphosphoramidite 

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References

  1. 1.
    C. A. Tolman,Chem. Rev., 1977,77, 313.CrossRefGoogle Scholar
  2. 2.
    G. K. Anderson, H. C. Clark, and J. A. Davies,Inorg. Chem., 1981,20, 3607.CrossRefGoogle Scholar
  3. 3.
    I. M. Al-Najjar,Inorg. Chim. Acta., 1987,128, 93.CrossRefGoogle Scholar
  4. 4.
    D. Bernard and R. Burgada,Phosphorus, 1974,3, 187.Google Scholar
  5. 5.
    E. E. Nifant'ev, E. N. Rasadkina, and I. D. Rozhdestvenskaya,Koord. Khim., 1979,5, 1846 [Sov. J. Coord. Chem., 1979,5 (Engl. Transl.)].Google Scholar
  6. 6.
    V. S. Reddy, K. V. Katti, and C. L. Barnes,Inorg. Chem., 1995,34, 5483.CrossRefGoogle Scholar
  7. 7.
    S. D. Pastor and A. Togni,Inorg. Chim. Acta, 1989,159, 3.CrossRefGoogle Scholar
  8. 8.
    N. Ahmad, E. W. Ainscough, T. A. James, and S. D. Robinson,J. Chem. Soc., Dalton Trans., 1973, 1148.Google Scholar
  9. 9.
    M. F. Rettig, R. M. Wing, and G. R. Wiger,J. Am. Chem. Soc., 1981,103, 2980.CrossRefGoogle Scholar
  10. 10.
    M. H. Rakowsky, J. C. Woolcock, L. L. Wright, D. B. Green, M. F. Rettig, and R. M. Wing,Organometallics, 1987,6, 1211.CrossRefGoogle Scholar
  11. 11.
    K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986.Google Scholar
  12. 12.
    A. Albinati, F. Lianza, H. Berger, P. S. Pregosin, H. Rüegger, and R. W. Kunz,Inorg. Chem., 1993,32, 478.CrossRefGoogle Scholar
  13. 13.
    R. G. Goodfellow, P. L. Goggin, and L. M. Venanzi,J. Chem. Soc., A, 1967, 1897.Google Scholar
  14. 14.
    R. G. Goodfellow, J. G. Evans, P. L. Goggin, and D. A. Duddell,J. Chem. Soc., A, 1968, 1604.Google Scholar
  15. 15.
    D. M. Adams and P. J. Chandler,J. Chem. Soc., A, 1969, 588.Google Scholar
  16. 16.
    D. A. Duddell, P. L. Goggin, R. G. Goodfellow, M. G. Norton, and J. G. Smith,J. Chem. Soc., A, 1970, 545.Google Scholar
  17. 17.
    K. N. Gavrilov, I. S. Mikhel, K. A. Lysenko, M. Yu. Antipin, G. I. Timofeeva, A. I. Polosukhin, and A. V. Korostylev,Zh. Neorg. Khim., 1997.42, 593 [Russ. J. Inorg. Chem., 1997,42, 520 (Engl. Transl.)].Google Scholar
  18. 18.
    C. Reichardt,Solvents and Solvent Effects in Organic Chemistry, VCH, Weinheim, 1988.Google Scholar
  19. 19.
    D. Drew and J. R. Doyle,Inorg. Synth., 1972,13, 52.Google Scholar
  20. 20.
    H. C. Clark and L. E. Manzer,J. Organomet. Chem., 1973,59, 411.CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • I. S. Mikhel
    • 1
  • K. N. Gavrilov
    • 1
  • A. I. Polosukhin
    • 2
  • A. I. Rebrov
    • 3
  1. 1.S. A. Esenin Ryazan' State Pedagogical UniversityRyazan'Russian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.A. V. Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussian Federation

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