Russian Chemical Bulletin

, Volume 47, Issue 8, pp 1446–1450 | Cite as

Dynamics of joint adsorption of mutually soluble substances by activated carbons

  • E. A. Ustinov
  • N. S. Polyakov
  • M. L. Gubkina
Physical Chemistry

Abstract

A model for the dynamics of isothermal absorption of a binary mixture of an organic substance, soluble in water, and water vapor in a fixed bed of activated carbon was proposed. It includes the equations of material balance and the Myers—Prausnitz model for equilibrium adsorption. The possibility of formation of the condensed phase during the adsorption of an organic substance on moist activated carbon was shown.

Key words

dynamics of isothermal adsorption activated carbon mutually soluble substances 

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References

  1. 1.
    A. A. Zhukhovitskii, Ya. L. Zabezhinskii, and A. N. Tikhonov,Zh. Fiz. Khim., 1945,19, 253 [Russ. J. Phys. Chem., 1945,19 (Engl. Transl.)].Google Scholar
  2. 2.
    A. N. Tikhonov, A. A. Zhukhovitskii, and Ya. L. Zabezhinskii,Zh. Fiz. Khim., 1949,23, 192 [Russ. J. Phys. Chem., 1949,23 (Engl. Transl.)].Google Scholar
  3. 3.
    P. P. Zolotarev and A. I. Kalinichev,Dokl. Akad. Nauk SSSR, 1971,199, 1098 [Dokl. Chem., 1971 (Engl. Transl.)].Google Scholar
  4. 4.
    M. M. Dubinin, K. M. Nikolaev, N. S. Polyakov, and L. I. Petrova,Izv. Akad. Nauk SSSR, Ser. Khim., 1972, 1265 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972,21, 1223 (Engl. Transl.)].Google Scholar
  5. 5.
    E. A. Ustinov, N. S. Polyakov, K. M. Nikolaev, and M. M. Dubinin,Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 49 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981,30 (Engl. Transl.)].Google Scholar
  6. 6.
    G. B. Freeman and P. J. Reucroft,Carbon, 1979,17, 313.CrossRefGoogle Scholar
  7. 7.
    L. B. Adams, C. R. Hall, R. J. Holmes, and R. A. Newton,Carbon, 1988,26, 451.CrossRefGoogle Scholar
  8. 8.
    V. S. Kut'kov and N. S. Polyakov,Izv. Akad. Nauk, Ser. Khim., 1994, 1398 [Russ. Chem. Bull., 1994,43, 1324 (Engl. Transl.)].Google Scholar
  9. 9.
    V. S. Kut'kov and N. S. Polyakov,Izv. Akad. Nauk, Ser. Khim., 1995, 62 [Russ. Chem. Bull., 1995,44, 56 (Engl. Transl.)].Google Scholar
  10. 10.
    O. M. Todes and Ya. M. Bikson,Dokl. Akad. Nauk SSSR, 1950,75, 727 [Dokl. Chem., 1950 (Engl. Transl.)].Google Scholar
  11. 11.
    Ya. M. Bikson,Zh. Fiz. Khim., 1953,27, 1530 [Russ. J. Phys. Chem., 1953,27 (Engl. Transl.)].Google Scholar
  12. 12.
    E. A. Ustinov,Zh. Prikl. Khim., 1980,53, 136 [J. Appl. Chem. USSR, 1980,53 (Engl. Transl.)].Google Scholar
  13. 13.
    E. A. Ustinov,Zh. Prikl. Khim., 1980,53, 2015 [J. Appl. Chem. USSR, 1980,53 (Engl. Transl.)].Google Scholar
  14. 14.
    A. L. Myers and J. M. Prausnitz,Am. Inst. Chem. Eng. J., 1965,11, 121.Google Scholar
  15. 15.
    M. M. Dubinin and V. V. Radushkevich,Dokl. Akad. Nauk SSSR, 1954,99, 1033 [Dokl. Chem., 1954,99 (Engl. Transl.)].Google Scholar
  16. 16.
    M. M. Dubinin and V. V. Serpinskii,Dokl. Akad. Nauk SSSR, 1981,258, 1151 [Dokl. Chem., 1981,258 (Engl. Transl.)].Google Scholar
  17. 17.
    E. A. Ustinov,Zh. Fiz. Khim., 1997,71, 118 [Russ. J. Phys. Chem., 1997,71 (Engl. Transl.)].Google Scholar
  18. 18.
    V. A. Bakaev,Dokl. Akad. Nauk SSSR, 1966,167, 369 [Dokl. Chem., 1966,167 (Engl. Transl.)].Google Scholar

Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • E. A. Ustinov
    • 1
  • N. S. Polyakov
    • 2
  • M. L. Gubkina
    • 2
  1. 1.St. Petersburg State Technological InstituteSt. PetersburgRussian Federation
  2. 2.Institute of Physical ChemistryRussian Academy of SciencesMoscowRussian Federation

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