Skip to main content
SpringerLink
Log in

Reaction of lithium acetylides with car-3-ene-2,5-dione

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The reaction of car-3-ene-2,5-dione (1), an oxidation product of (+)-car-3-ene, with lithium acetylides proceeds stereospecifically, but not regioselectively, to give only mixtures of regioisomeric acetylenic alcohols with thesyn-orientation of the hydroxy group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. D. P. Popa and K. I. Kuchkova,Analogi abstsizovoi kisloty [Analogs of Abscisic Acid], Shtiintsa, Kishinev, 1982 (in Russian).

    Google Scholar 

  2. M. Soukup, T. Lukac, B. Lohri, and E. Widmer,Helv. Chim. Acta, 1989,72, 361.

    Article  CAS  Google Scholar 

  3. A. Fischer and G. N. Henderson,Tetrahedron Lett., 1980,21, 701.

    Article  CAS  Google Scholar 

  4. D. Liotta, M. Saindane, and C. Barnum,J. Org. Chem., 1981,46, 3369.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    F. Z. Galin, Yu. A. Kashina, R. A. Zainullin, O. S. Kukovinets, L. M. Khalilov & G. A. Tolstikov

Authors
  1. F. Z. Galin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. A. Kashina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. A. Zainullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. S. Kukovinets
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. M. Khalilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. A. Tolstikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 183–185, January, 1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Galin, F.Z., Kashina, Y.A., Zainullin, R.A. et al. Reaction of lithium acetylides with car-3-ene-2,5-dione. Russ Chem Bull 47, 185–186 (1998). https://doi.org/10.1007/BF02495533

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02495533

Key words

Search

Navigation