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Reaction of 4-methyl-4-tribromomethylcyclohexa-2,5-dien-1-one with zinc metal

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Abstract

4-Methyl-4-tribromomethylcyclohexa-2,5-dien-1-one reacts with zinc dust in absolute DMF to give a mixture of 4-bromo-5-methylcyclohepta-2,4,6-trien-1-one, 4-methyl-cyclohepta-2,4,6-trien-1-one, and 4-dibromomethyl-4-methylcyclohexa-2,5-dien-1-one.

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References

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 177–178, January, 1998.

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Gavrilova, G.V., Gavrilov, A.A. & Butin, K.P. Reaction of 4-methyl-4-tribromomethylcyclohexa-2,5-dien-1-one with zinc metal. Russ Chem Bull 47, 179–180 (1998). https://doi.org/10.1007/BF02495530

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  • DOI: https://doi.org/10.1007/BF02495530

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