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(4R,5R)-Bis(N,N-dimethylaminocarbonyl)-2-chloro-1,3,2-dioxaphospholane: A convenient reagent for control of enantiomeric composition of chiral alcohols by31P NMR spectroscopy

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Abstract

The use of enantiomerically pure cyclic chlorophosphite obtained by the reaction of PCl3 withN,N,N′,N′-tetramethyldiamide of naturall-(+)-tartaric acid for analysis of the enantiomeric composition of chiral primary and secondary alcohols by31P NMR spectroscopy is considered.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan, Russian Federation

    A. A. Bredikhin, E. I. Strunskaya, N. M. Azancheev & Z. A. Bredikhina

Authors
  1. A. A. Bredikhin
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  2. E. I. Strunskaya
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  3. N. M. Azancheev
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  4. Z. A. Bredikhina
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Translated fromIzvestiya Akademii Nauk., Seriya Khimicheskaya, No. 1, pp. 172–175, January, 1998.

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Bredikhin, A.A., Strunskaya, E.I., Azancheev, N.M. et al. (4R,5R)-Bis(N,N-dimethylaminocarbonyl)-2-chloro-1,3,2-dioxaphospholane: A convenient reagent for control of enantiomeric composition of chiral alcohols by31P NMR spectroscopy. Russ Chem Bull 47, 174–176 (1998). https://doi.org/10.1007/BF02495528

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  • DOI: https://doi.org/10.1007/BF02495528

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