Russian Chemical Bulletin

, Volume 49, Issue 4, pp 666–668 | Cite as

Photochemistry of arylhydrazides in solution

  • D. G. Belov
  • B. G. Rogachev
  • L. I. Tkachenko
  • V. A. Smirnov
  • S. M. Aldoshin
Physical Chemistry

Abstract

The photochemical reactions of arylhydrazides ArCONHN=CHR in solution were studied. The main photochemical process was shown to betrans-cis isomerization with a quantum yield of 0.2–0.8 and an activation energy of 21–24 kcal mol−1.

Key words

photochemical reactions arylhydrazides quantum yield trans-cis isomerization luminescence activation energy 

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Copyright information

© Kluwer Academic/Plenum Publishers 2000

Authors and Affiliations

  • D. G. Belov
    • 1
  • B. G. Rogachev
    • 1
  • L. I. Tkachenko
    • 1
  • V. A. Smirnov
    • 1
  • S. M. Aldoshin
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation

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