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Russian Chemical Bulletin

, Volume 46, Issue 3, pp 592–594 | Cite as

Reactions of 1-aryl-2-bromodiazene 1-oxides with acids and bases

  • A. Yu. Tyurin
  • A. M. Churakov
  • S. L. Ioffe
  • Yu. A. Strelenko
  • V. A. Tartakovsky
Brief Communications

Abstract

The reactions of 1-aryl-2-bromodiazene 1-oxides with HCl in nonaqueous media give aryldiazonium chlorides, while 1,3,3-substituted triazenes-1 are formed in the reactions with secondary amines. Using 2-{15N} label, it was shown that the aryl group does not migrate in these reactions.

Key words

1-aryl-2-bromodiazene 1-oxides diazonium salts triazenes 15N NMR spectroscopy 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • A. Yu. Tyurin
    • 1
  • A. M. Churakov
    • 1
  • S. L. Ioffe
    • 1
  • Yu. A. Strelenko
    • 1
  • V. A. Tartakovsky
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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