Russian Chemical Bulletin

, Volume 46, Issue 3, pp 572–576 | Cite as

19F NMR study of comparative polarity of metal—oxygen and metal—sulfur bonds formed bytrans-2-CH3C6H4M(PEt3)2 (M=Ni, Pd, Pt) groups

  • D. N. Kravtsov
  • A. S. Peregudov
  • G. I. Drogunova
Organometallic Chemistry


A series of organometallic 4-fluorophenoxides, 4-fluorobenzoates, and 4-fluorothiophenoxides containingtrans-2-CH3C6H4M(PEt3)2 (M=Ni, Pd, Pt) groups was synthesized. Based on the19F NMR study, the data on the comparative polarity of the M−O and M−S bonds and comparative electronegativity of the indicated groups were obtained. The results indicate that the group electronegativities do not change in parallel to the electronegativities of the centrla metal atoms, and their sequence may vary as the nature of the heteroatom bonded to these groups changes.

Key words

bond polarity electronegativity group electronegativity nickel palladium platinum 19F NMR spectra 


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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • D. N. Kravtsov
    • 1
  • A. S. Peregudov
    • 1
  • G. I. Drogunova
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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