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Chemistry of bicymantrenyl

6. Synthesis and properties of quatercymantrenyls with phosphine ligands

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Oxidative coupling of lithium derivatives of the (CO)2PPh3MnC5H4−C5H4Mn(CO)3 complex with CuCl2 results in the formation of four isomeric quatercymantrenyls containing two phosphine ligands. The compounds isolated were characterized by the1H and31P NMR spectra.

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References

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    S. V. Suprunovich, A. G. Ginzburg, E. V. Vorontsov & V. I. Sokolov

Authors
  1. S. V. Suprunovich
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  2. A. G. Ginzburg
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  3. E. V. Vorontsov
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  4. V. I. Sokolov
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Additional information

For Part 5, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 587–590, March, 1997.

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Suprunovich, S.V., Ginzburg, A.G., Vorontsov, E.V. et al. Chemistry of bicymantrenyl. Russ Chem Bull 46, 568–571 (1997). https://doi.org/10.1007/BF02495416

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  • DOI: https://doi.org/10.1007/BF02495416

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