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Russian Chemical Bulletin

, Volume 46, Issue 3, pp 528–531 | Cite as

Reactions of 1,6-anhydro-3,4-dideoxy-2-O-methyl-β-d-threo-hex-3-enopyranose with thiols and methanol

  • F. A. Valeev
  • I. N. Gaisina
  • L. V. Spirikhin
  • M. S. Miftakhov
Organic Chemistry
  • 29 Downloads

Abstract

Thiolysis and methanolysis of 1,6-anhydro-3,4-dideoxy-2-O-methyl-β-d-threo-hex-3-enopyranose yield anomeric thio- and methyl glycosides, respectively, and an acyclic product (in the reaction with EtSH).

Key words

hex-3-enopyranose anomers thiols allylic carbocations substitution 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • F. A. Valeev
    • 1
  • I. N. Gaisina
    • 1
  • L. V. Spirikhin
    • 1
  • M. S. Miftakhov
    • 1
  1. 1.Institute of Organic ChemistryUfa Research Center of the Russian Academy of SciencesUfaRussian Federation

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