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Crown-containing styryl dyes

19. Complexation and cation-induced aggregation of chromogenic aza-15-crown-5 ethers

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Complexation of styryl dyes containing theN-phenylaza-15-crown-5 fragment (trans-2a,b) with Ca2+ ions in MeCN was studied. Unlike cationic dyetrans-2a, betainetrans-2b forms both complexes of 1∶1 stoichiometry and aggregates consisting of four dye molecules and one Ca2+ ion. Cation-induced aggregation was observed also for the analog of dyetrans-2b, which contains a dimethylamino group instead of an azacrown ether fragment (trans-3). Apparently, the interaction between a metal cation and sulfo groups of moleculestrans-2b ortrans-3 makes the main contribution to the stability of aggregates. The dependence of the stability of aggregates on the nature of the metal cation was studied.

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Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation

    E. N. Ushakov

  2. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 7A, ul. Novatorov, 117421, Moscow, Russian Federation

    S. P. Gromov, O. A. Fedorova & M. V. Alfimov

Authors
  1. E. N. Ushakov
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  2. S. P. Gromov
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  3. O. A. Fedorova
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  4. M. V. Alfimov
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Additional information

For Communication 18, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 484–492, March, 1997.

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Ushakov, E.N., Gromov, S.P., Fedorova, O.A. et al. Crown-containing styryl dyes. Russ Chem Bull 46, 463–471 (1997). https://doi.org/10.1007/BF02495396

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  • DOI: https://doi.org/10.1007/BF02495396

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