Abstract
Planar chiral 2- and 3-bicymantrenylcarbaldehydes can be resolved to enantiomers through Schiff's bases with (S)-(−)-α-phenylethylamine. Optically active derivatives of bicymantrenyl with Me and CH2OH substituents were synthesized from (−)-3-bicymantrenylcarbaldehyde. The absolute configuration of Schiff's base obtained from (+)-3-bicymantrenylcarbaldehyde was determined by X-ray diffraction analysis.
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For Part 3, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 158–162, January, 1997.
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Suprunovich, S.V., Loim, N.M., Dolgushin, F.M. et al. Bicymantrenyl chemistry. Russ Chem Bull 46, 154–158 (1997). https://doi.org/10.1007/BF02495365
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DOI: https://doi.org/10.1007/BF02495365