Abstract
Compounds C60(S4N4)2−x (C6H6) x (1a-d) withx=0.67 (a), 1.0 (b), 1.1 (c), and 1.2 (d), in which isomorphous replacement of S4N4 with benzene takes place, were obtained by the reaction of fullerence C60 with tetrasulfur tetranitride in benzene. Complexes C60·S4N4 (2) and C60(S4N4)2 (3) containing no solvent were isolated from toluene. The compositions of the compounds were established by elemental and thermogravimetric analyses. The data of IR and X-ray photoelectron (XP) spectroscopies show that in the complexes studied the transfer of electron density occurs mainly from the nitrogen atoms of S4N4.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. F., Hebard, M. J. Rosseinsky, R. C. Haddon, D. W. Murphy, S. H. Glarum, T. T. Palstra, A. P. Ramirez, and A. R. Kortan,Nature, 1991,350, 600.
P. W. Stephens, D. Cox, J. W. Lauher, L. Mihaly, J. B. Wiley, P. Allemand, A. Hirsch, K. Holczer, Q. Li, J. D. Thompson, and F. Wudl,Nature, 1992,355, 331.
A. Izuoka, T. Tachikawa, T. Sugawara, Y. Suzuki, M. Konno, Y. Saito, and H. Shinohara,J. Chem. Soc., Chem. Commun., 1992, 1472.
D. V. Konarev, R. N. Lyubovskaya, O. S. Roshchupkina, and Yu. M. Shul'ga,Izv. Akad. Nauk, Ser. Khim., 1995, 2068 [Russ. Chem. Bull., 1995,44, 1984 (Engl. Transl.)].
D. V. Konarev, R. N. Lyubovskaya, O. S. Roshchupkina, Y. M. Shul'ga, M. G. Kaplunov, I. N. Kremenskaya, L. P. Rozenberg, S. S. Hasanov, and R. P. Shibaeva,Mendeleev Commun. 1996, 3.
G. Saito, T. Teramoto, A. Otsuka, Y. Sugita, T. Ban, M. Kusunoki, and K. Saakaaguchi,Synth. Met., 1994,64, 359.
J. D. Crane, P. B. Hitchcock, H. W. Kroto, R. Taylor, and D. R. Walton,J. Chem. Soc., Chem. Commun., 1992, 1764.
L. I. Buravov, O. A. D'yachenko, S. V. Konovalikhin, N. D. Kushch, I. P. Lavrent'ev, N. G. Spitsyna, G. V. Shilov, and E. B. Yagubskii,Izv. Akad. Nauk, Ser. Khim., 1994, 262 [Russ. Chem. Bull., 1994,43, 240 (Engl. Transl.)].
N. D. Kushch, I. Majchrzak, W. Ciesielski, and A. Graja,Chem. Phys. Lett., 1993,215, 137.
R. E. Douthwaite, M. L. H. Green, S. J. Heyes, M. J. Roseinsky, and J. F. C. Turner,J. Chem. Soc., Chem. Commun., 1994, 1367.
Yu. M. Shul'ga, V. I. Rubtsov, V. N. Vasilets, A. S. Lobach, N. G. Spitsyna, and G. A. Volkov,Izv. Akad. Nauk, Ser. Khim., 1994, 2149 [Russ. Chem. Bull., 1994,43, 2030 (Engl. Transl.)].
M. L. DeLucia and P. Coppens,Inorg. Chem., 1978,17, 2336.
M. R. Brinkman and C. W. Allen,J. Am. Chem. Soc., 1972, 94, 1550.
M. Becker-Goering und D. Schlafer,Z. anorg. und allg. Chem., 1965,77, 262.
Kratkaya khimicheskaya entsiklopediya [Brief Chemical Encyclopedia], Sovetskaya Entsiklopediya, Moscow, 1965,4, 802 (in Russian).
E. R. Lippincott and M. C. Tobin,J. Chem. Phys., 1953,21, 1559.
V. I. Nefedov inRentgenoelektronnaya spektroskopiya khimicheskikh soedinenii [X-ray Electron Spectroscopy of Chemical Compounds]. Khimiya, Moscow, 1984, 256 (in Russian).
D. V. Konarev, E. F. Valeev, Yu. L. Slovokhotov, and R. N. Lyubovskaya,J. Chem. Phys. Solids, 1997, in press.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 37–40. January 1977.
Rights and permissions
About this article
Cite this article
Konarev, D.V., Lyubovskaga, R.N., Roshchupkina, O.S. et al. Molecular complexes of C60 with tetrasulfur tetranitride. Russ Chem Bull 46, 32–35 (1997). https://doi.org/10.1007/BF02495342
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02495342