Skip to main content
SpringerLink
Log in

A differential method for the analysis of chemical kinetics results based on reversed-flow gas chromatography

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The reversed-flow gas chromatographic technique has been applied to the determination of the apparent rate constant and the reaction order of a reaction between two gases or vapors. For seven hydrocarbons (ethane, ethene, ethyne, propene, butene, benzene and toluene) reacting with nitrogen dioxide, the above mentioned kinetic parameters have been determined. For these determinations, the necessary mathematical formulation of the problem has been written and solved, leading to simple expressions which describe the height of the chromatographic sample peaks as a function of time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. A. Katsanos, E. Dalas, J. Phys. Chem.91, 3103 (1987).

    Article  CAS  Google Scholar 

  2. N. A. Katsanos, “Flow Perturbation Gas Chromatography”, Marcel Dekker, New York-Basel, 1988.

    Google Scholar 

  3. F Roubani-Kalantzopoulou, H. Metaxa, A. Kalantzopoulos, N. A. Katsanos, Proceedings of LCP 95 Congress, Preservation and Restoration of Cultural Heritáge: Montreux Switzerland, 1995, p. 393.

  4. V. Sotiropoulou, G. P. Vassilev, N. A. Katsanos, H. Metaxa, F. Roubani-Kalantzopoulou, J. Chem. Soc. Faraday Trans.91, 485 (1995).

    Article  CAS  Google Scholar 

  5. I. Topalova, N. A. Katsanos, J. Kapolos, Ch. Vassilakos, Atmos. Environ.28, 1791 (1994).

    Article  CAS  Google Scholar 

  6. E. Arvanitopoulou, N. A. Katsanos, H. Metaxa, F. Roubani-Kalantzopoulou, Atmos. Environ.28, 2407 (1994).

    Article  CAS  Google Scholar 

  7. N. A. Katsanos, F. Roubani-Kalantzopoulou, J. Chromatogr. A710, 191 (1995).

    Article  CAS  Google Scholar 

  8. N. A. Katsanos, Ch. Vassilakos, J. Chromatogr.557, 469 (1991).

    Article  CAS  Google Scholar 

  9. Ch. Vassilakos, N. A. Katsanos, A. Niotis, Atmos. Environ.26A, 219 (1992).

    CAS  Google Scholar 

  10. A. Kalantzopoulos, F. Roubani-Kalantzopoulou, J. Kapolos, N. A. Katsanos, Proceedings of 4th Panhellenic Symposium on Catalysis, Papigo Greece, 1994, p. 45.

  11. V. Sotiropoulou, N. A. Katsanos, H. Metaxa, F. Roubani-Kalantzopoulou, Chromatographia42, 441 (1996).

    Article  CAS  Google Scholar 

  12. N. A. Katsanos, G. Karaiskakis, J. Chromatogr.237, 1 (1982).

    Article  CAS  Google Scholar 

  13. N. A. Katsanos, P. Agathonos, A. Niotis, J. Phys. Chem.92, 1645 (1988).

    Article  CAS  Google Scholar 

  14. N. A. Katsanos, J. Kapolos, Anal. Chem.61, 2231 (1989).

    Article  CAS  Google Scholar 

  15. S. C. Chao, S. Jaffe, J. Chem. Phys.56, 1987 (1972).

    Article  CAS  Google Scholar 

  16. T. L. Cottrell, T. E. Graham, J. Chem. Soc. 556 (1953).

  17. R. Atkinson, S. M. Ashmann, A. M. Winer, J. N. Pitts (Jr.), Int. J. Chem. Kinet.16, 697 (1984).

    Article  CAS  Google Scholar 

  18. J. L. Sprung, H. Akimoto, J. N. Pitts (Jr.), J. Am. Chem. Soc.21, 6549 (1974).

    Article  Google Scholar 

Download references

Author information

Author notes

  1. R. Thede

    Present address: Fachbereich Chemie, University of Greifswald, Soldtmannstrasse 23, 17489, Greifswald, Germany

Authors and Affiliations

  1. Department of Chemical Engineering, National Technical University of Athens, 157 80, Zografou, Greece

    F. Roubani-Kalantzopoulou, E. Kalogirou, A. Kalantzopoulos & H. Metaxa

  2. Physical Chemistry Laboratory, University of Patras, 265 00, Patras, Greece

    N. A. Katsanos & V. Sotiropoulou

Authors
  1. F. Roubani-Kalantzopoulou
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Kalogirou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Kalantzopoulos
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Metaxa
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. Thede
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. A. Katsanos
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. Sotiropoulou
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Roubani-Kalantzopoulou, F., Kalogirou, E., Kalantzopoulos, A. et al. A differential method for the analysis of chemical kinetics results based on reversed-flow gas chromatography. Chromatographia 46, 161–169 (1997). https://doi.org/10.1007/BF02495328

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02495328

Key Words

Search

Navigation