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Highly stereoselective synthesis of a sex pheromone of the dry bean beetleCallosobruchus analis

  • Chemistry of Natural Compounds and Bioorganic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Total synthesis of 3-methylhept-2(Z)-enoic acid, a sex pheromone of the dry bean beetleCallosobruchus analis, has been performed using a previously developed highly stereoselective method of the construction of disubstituted (Z)-methylolefins based on the higher thermodynamic stability of (E)-isomers of α,β-disubstituted acroleins.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    O. A. Pinsker, P. G. Tsiklauri & N. Ya. Grigor'eva

Authors
  1. O. A. Pinsker
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  2. P. G. Tsiklauri
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  3. N. Ya. Grigor'eva
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1385–1388, July, 1999.

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Pinsker, O.A., Tsiklauri, P.G. & Grigor'eva, N.Y. Highly stereoselective synthesis of a sex pheromone of the dry bean beetleCallosobruchus analis . Russ Chem Bull 48, 1373–1375 (1999). https://doi.org/10.1007/BF02495308

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  • DOI: https://doi.org/10.1007/BF02495308

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