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Synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The previously unknown metallacarboranes (η-C5R5)Ru(η-9-Me2S-7,8-C2B9H10) (R=H or Me) and (η-C5H5)Ni(η-9-Me2S-7,8-C2B9H10) were prepared and used in the synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand, viz., [(η-C5R5)Ru(μ-η:η-C5Me5)Ru(η-9-Me2S-7,8-C2B9H10)]PF6 (R=H or Me), [(η-9-Me2S-7,8-C2B9H10)Ni(μ-η:η-C5H5)Ni(η-9-Me2S-7,8-C2B9H10)]PF6, and [(η-C5H5)Ni(μ-η:η-C5H5)Ni(η-9-Me2S-7,8-C2B9H10)]BF4.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. R. Kudinov, P. V. Petrovskii, V. I. Meshcheryakov & M. I. Rybinskaya

Authors
  1. A. R. Kudinov
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  2. P. V. Petrovskii
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  3. V. I. Meshcheryakov
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  4. M. I. Rybinskaya
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1368–1373, July, 1999.

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Kudinov, A.R., Petrovskii, P.V., Meshcheryakov, V.I. et al. Synthesis of the first metallacarborane triple-decker complexes with a central cyclopentadienyl ligand. Russ Chem Bull 48, 1356–1361 (1999). https://doi.org/10.1007/BF02495304

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  • DOI: https://doi.org/10.1007/BF02495304

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