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Iodination of nitroarenes by a superactive reagent based on iodine chloride

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Iodine chloride reacts with Ag2SO3 in H2SO4 to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0–20°C, while dinitroarenes require heating to 100–170°C.

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Authors and Affiliations

  1. Department of Organic Chemistry, Tomsk Polytechnic University, 30 prosp. Lenina, 634004, Tomsk, Russian Federation

    V. K. Chaikovskii, T. S. Kharlova & V. D. Filimnov

Authors
  1. V. K. Chaikovskii
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  2. T. S. Kharlova
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  3. V. D. Filimnov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1303–1306, July, 1999.

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Chaikovskii, V.K., Kharlova, T.S. & Filimnov, V.D. Iodination of nitroarenes by a superactive reagent based on iodine chloride. Russ Chem Bull 48, 1291–1294 (1999). https://doi.org/10.1007/BF02495292

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  • DOI: https://doi.org/10.1007/BF02495292

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