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Hypercoordinated gold(I) compounds

4. synthesis and structure of anortho-diaurated 4-tert-butylbiphenyl derivative

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

A hypercoordinated 2,2′-diaurated 4-tert-butylbiphenyl derivative, which contains an intramolecular Au...Au secondary bond, was first synthesized by the reaction of 2,2′-dilithio-4-tert-butylbiphenyl with ClAuPPh3. The structure of the complex was established by X-ray structural analysis,1H and31P NMR spectroscopy, and fast-atom bombardment mass spectrometry.

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References

  1. T. V. Baukova, L. G., Kuz'mina, N. A. Oleinikova, and D. A. Lemenovskii,Izv. Akad. Nauk, Ser. Khim., 1995, 2032 [Russ. Chem. Bull., 1995,44, 1962 (Engl. Transl.)].

  2. A. Grohmann and H. Schmidbaur,Comprehensive Organometallic Chemistry, II, Eds. E. W. Abel, F. Q. A. Stone, and Q. Wilkinson, Pergamon Press, 1995,3, 12.

  3. L. G. Kuz'mina, Dr. Sc. (Chem.) Thesis, N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 1990, 394 pp. (in Russian).

  4. T. V. Baukova, Dr. Sc. (Chem.) Thesis, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 1996, 24 (in Russian).

  5. H. Smidbaur, F. P. Qabbai, and A. J. Riede,Organometallics, 1995,14, 4969.

    Article  Google Scholar 

  6. J. Li and P. Pyykko,Inorg. Chem., 1993,32, 2630.

    Article  CAS  Google Scholar 

  7. Y. Jiang, S. Alvarez, and R. Hoffman,Inorg. Chem., 1985,24, 749.

    Article  CAS  Google Scholar 

  8. V. P. Dyadchenko, P. E. Krasik, K. I. Grandberg, L. G. Kuz'mina, N. V. Dvortsova, M. A. Porai-Koshits, and E. G. Perevalova,Metalloorg. Khim., 1990,3, 1260 [Organomet. Chem. USSR, 1990,3, 654 (Engl. Transl.)].

    CAS  Google Scholar 

  9. T. V. Baukova, N. A. Oleinikova, D. A. Lemenovskii, and L. G. Kuz'mina,Izv. Akad. Nauk, Ser. Khim., 1994, 729 [Russ. Chem. Bull., 1994,43, 681 (Engl. Transl.)].

    Google Scholar 

  10. T. V. Baukova, V. P. Dyadchenko, N. A. Oleinikova, D. A. Lemenovskii, and L. G. Kuz'mina,Izv. Akad. Nauk, Ser. Khim., 1994, 1125 [Russ. Chem. Bull., 1994,43, 1063 (Engl. Transl.)].

    Google Scholar 

  11. T. V. Baukova, L. G. Kuz'mina, N. A. Oleinikova, D. A. Lemenovskii, and A. L. Blumenfel'dJ. Organomet. Chem., 1997,530, 27.

    Article  CAS  Google Scholar 

  12. O. Bastiasen,Acta Chem. Scand., 1949, 408.

  13. P. Singh, M. Posner, and J. Mc. Kinney,Acta Crystallogr., 1987,C47, 106.

    Google Scholar 

  14. A. Bondi,J. Phys., 1964,68, 441.

    CAS  Google Scholar 

  15. L. G. Kuz'mina, O. Yu. Burtseva, N. V. Dvortsova, M. A. Porai-Koshits, and E. I. Smyslova,Koord. Khim., 1989,15, 773 [Sov. J. Coord. Chem., 1989,15 (Engl. Transl.)].

    Google Scholar 

  16. P. Pyykko and Y. Zhao,Angew. Chem., Int. Ed. Engl., 1991,30, 604.

    Article  Google Scholar 

  17. E. Rothstein and R. W. Savill,J. Chem. Soc., 1949, 1950.

  18. C. Kowala and I. M. Swan,Aust. J. Chem., 1996,19, 547.

    Article  Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    T. V. Baukova

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    L. G. Kuzmina & A. V. Churakov

Authors
  1. T. V. Baukova
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  2. L. G. Kuzmina
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  3. A. V. Churakov
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Additional information

For Part 3, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2244–2247, December, 1997.

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Baukova, T.V., Kuzmina, L.G. & Churakov, A.V. Hypercoordinated gold(I) compounds. Russ Chem Bull 46, 2127–2129 (1997). https://doi.org/10.1007/BF02495267

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  • DOI: https://doi.org/10.1007/BF02495267

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