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Synthesis and crystal structure of 7,7,10-trimethyl-7-silabenzo[a]anthrone

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Skeletal isomerization of arylsilanes that occurs under conditions of catalytic dehydrocyclization and is accompanied by migration of the triorganosilyl group was additionally confirmed by dehydrocyclization of dimethyl(2,4-dimethylphenyl)(1-naphthyl)silane on chromium-containing oxide catalysts.

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Authors and Affiliations

  1. State Scientific Research Institute of Reagents and Extra Pure Chemicals, 3 Bogorodsky val, 107076, Moscow, Russian Federation

    V. M. Polosin

  2. Russian People's Frendship University, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation

    A. A. Astakhov

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    M. A. Ryashentseva

  4. Department of Chemistry, M. V. Lomonosov Moscow State University, Vorob'evy Gory, 119899, Moscow, Russian Federation

    V. A. Tafeenko

Authors
  1. V. M. Polosin
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  2. A. A. Astakhov
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  3. M. A. Ryashentseva
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  4. V. A. Tafeenko
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2236–2239, December, 1997.

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Polosin, V.M., Astakhov, A.A., Ryashentseva, M.A. et al. Synthesis and crystal structure of 7,7,10-trimethyl-7-silabenzo[a]anthrone. Russ Chem Bull 46, 2121–2123 (1997). https://doi.org/10.1007/BF02495265

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  • DOI: https://doi.org/10.1007/BF02495265

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