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Synthesis of 3-amino-5-nitrobenzaldehyde oxime and its conversion into 3,4-bis(3-amino-5-nitrophenyl)furoxan and isomeric 3(4)-(3-amino-5-nitrophenyl)-4(3)-nitrofuroxans

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The oxime of the hitherto unknown 3-amino-5-nitrobenzaldehyde was synthesized by the reaction of 3-amino-5-nitrobenzaldehyde phenylhydrazone with excess of (NH2OH)2·H2SO4. The oxime obtained was used as the starting compound for the synthesis of novel diaryl- and arylnitrofuroxans.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    M. A. Epishina, I. V. Ovchinnikov & N. N. Makhova

Authors
  1. M. A. Epishina
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  2. I. V. Ovchinnikov
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  3. N. N. Makhova
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2232–2235, December, 1997.

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Epishina, M.A., Ovchinnikov, I.V. & Makhova, N.N. Synthesis of 3-amino-5-nitrobenzaldehyde oxime and its conversion into 3,4-bis(3-amino-5-nitrophenyl)furoxan and isomeric 3(4)-(3-amino-5-nitrophenyl)-4(3)-nitrofuroxans. Russ Chem Bull 46, 2117–2120 (1997). https://doi.org/10.1007/BF02495264

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  • DOI: https://doi.org/10.1007/BF02495264

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