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Description of adsorption of haloalkanes and haloarenes on graphitized thermal carbon black by means of the model of an ideal two-dimensional gas

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The standard entropies theoretically calculated for 40 haloalkanes and haloarenes adsorbed on graphitized thermal carbon black were compared with those determined from the adsorption-chromatographic data. It was found that a molecular model of an ideal two-dimensional gas is a sufficiently good approximation in all the cases. For a number of systems, agreement can be improved by taking into account the vibrations of the center of the molecular mass relative to the surface.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Vorob'evy Gory, 119899, Moscow, Russian Federation

    E. V. Kalashnikova & A. A. Lopatkin

Authors
  1. E. V. Kalashnikova
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  2. A. A. Lopatkin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2173–2176, December, 1997.

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Kalashnikova, E.V., Lopatkin, A.A. Description of adsorption of haloalkanes and haloarenes on graphitized thermal carbon black by means of the model of an ideal two-dimensional gas. Russ Chem Bull 46, 2060–2063 (1997). https://doi.org/10.1007/BF02495252

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  • DOI: https://doi.org/10.1007/BF02495252

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