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Electrochemical activation of the alkylation of GeI2 byn-butyl bromide and methylcobalt(iii) bisdimethylglyoximate

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The mechanism of the alkylation of GeI2 byn-butyl bromide and methylcobalt(iii) bisdimethylglyoximate in acetonitrile was studied using cyclic voltammetry. The reaction with the methylcobalt complex occursvia anodic activation (oxidation of the methylcobalt complex), while the reaction withn-butyl bromide is initiated by cathodic activation (reduction of GeI2).

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Vorob'evy Gory, 119899, Moscow, Russian Federation

    R. D. Rakhimov & K. P. Butin

Authors
  1. R. D. Rakhimov
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  2. K. P. Butin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2157–2160, December, 1997.

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Rakhimov, R.D., Butin, K.P. Electrochemical activation of the alkylation of GeI2 byn-butyl bromide and methylcobalt(iii) bisdimethylglyoximate. Russ Chem Bull 46, 2044–2047 (1997). https://doi.org/10.1007/BF02495249

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  • DOI: https://doi.org/10.1007/BF02495249

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