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Experimental investigation and kinetic modeling of the negative temperature coefficient of the reaction rate in rich propane—oxygen mixtures

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The phenomenon of the negative temperature coefficient (NTC) of the reaction rate of the oxidation of rich propane—oxygen mixtures was experimentally studied. The NTC phenomenon is qualitatively described by a simple kinetic model containing a minimum set of reactions related to the oxidation of the starting hydrocarbon, propane, and the propyl C3H7 . radical formed.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    V. I. Vedeneev, L. B. Romanovich, V. Ya. Basevich, V. S. Arutyunov, O. V. Sokolov & Yu. V. Parfenov

Authors
  1. V. I. Vedeneev
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  2. L. B. Romanovich
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  3. V. Ya. Basevich
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  4. V. S. Arutyunov
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  5. O. V. Sokolov
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  6. Yu. V. Parfenov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2120–2124, December, 1997.

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Vedeneev, V.I., Romanovich, L.B., Basevich, V.Y. et al. Experimental investigation and kinetic modeling of the negative temperature coefficient of the reaction rate in rich propane—oxygen mixtures. Russ Chem Bull 46, 2006–2010 (1997). https://doi.org/10.1007/BF02495242

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  • DOI: https://doi.org/10.1007/BF02495242

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