Advertisement

Russian Chemical Bulletin

, Volume 46, Issue 4, pp 836–838 | Cite as

ESR study of radical adducts of dialkoxyphosphoryl radicals with (η2-C60)lrH(CO)(PPh3)2 and (η2-C60IrH(8H12)(PPh3)

  • B. L. Tumanskii
  • A. V. Usatov
  • V. V. Bashilov
  • S. P. Solodovnikov
  • N. N. Bubnov
  • Yu. N. Novikov
  • V. I. Sokolov
Brief Communications

Abstract

The reaction of phosphoryl radicals with (η2-C60)lrH(CO)(PPh3)2 and (η2-C60IrH(8H12)(PPh3) was shown (ESR) to result in the formation of isomers differing in the constants of hyperfine interaction (HFI) with31P nuclei,g-factors, and linewidths. It is likely that the addition of phosphoryl radicals at a distance of two-three bond lengths from the metallofragment is predominant.

Key words

ESR phosphoryl radical fullerenyl radical metallocomplex isomers 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    B. L. Tumanskii, V. V. Bashilov, N. N. Bubnov, S. P. Solodovnikov, and V. I. SokolovIzv. Akad. Nauk, Ser. Khim., 1994, 938 [Russ. Chem. Bull., 1994,43, 884 (Engl. Transl.)].Google Scholar
  2. 2.
    B. L. Tumanskii, M. N. Nefedova, V. V. Bashilov, N. N. Bubnov, S. P. Solodovnikov, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim., 1996, 3015 [Russ. Chem. Bull., 1996,45, 2865 (Engl. Transl.)].Google Scholar
  3. 3.
    A. V. Usatov, K. N. Kudin, E. V. Vorontsov, L. E. Vinogradova, and Yu. N. Novikov,J. Organomet. Chem., 1996,522, 147.CrossRefGoogle Scholar
  4. 4.
    A. V. Usatov, E. V. Vorontsov, L. E. Vinogradova, and Yu. N. Novikov,Izv. Akad. Nauk, Ser. Khim., 1994, 1661 [Russ. Chem. Bull. 1994,43, 1572 (Engl. Transl.)].Google Scholar
  5. 5.
    B. L. Tumanskii, V. V. Bashilov, S. P. Solodovnikov, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim., 1992, 1457 [Bull. Russ. Acad. Sci., Div. Chem. Sci. 1992,41, 1140 (Engl. Transl.)].Google Scholar
  6. 6.
    J. R. Morton, K. F. Preston, P. J. Krusic, S. A. Hill, and E. Wasserman,J. Phys. Chem., 1992,9, 3576.CrossRefGoogle Scholar
  7. 7.
    B. L. Tumanskii, V. V. Bashilov, E. N. Shaposhnikova, N. N. Bubnov, S. P. Solodovnikov, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim 1996, 2679 [Russ. Chem. Bull, 1996,45, 2530 (Engl. Transl.)].Google Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • B. L. Tumanskii
    • 1
  • A. V. Usatov
    • 1
  • V. V. Bashilov
    • 1
  • S. P. Solodovnikov
    • 1
  • N. N. Bubnov
    • 1
  • Yu. N. Novikov
    • 1
  • V. I. Sokolov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations