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Synthesis of triple-decker iron and cobalt complexes with a central tetramethylphospholyl ligand

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Abstract

30-Electron triple-decker complexes [(η-C5H5)Fe(μ-η:η-C4Me4P)Fe(η-C5Me5)]PF6 and [(η-C4Me4)Co(μ-η:η-C4Me4P)Fe(η-C5Me5)]PF6 with a central tetramethylphospholyl ligand were synthesized by stacking reactions of cationic fragments [(η-C5H5)Fe]+ and [(η-C4Me4)Co]+ with nonamethylphosphaferrocene (η-C4Me4P)Fe(η-C5Me5).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. R. Kudinov, D. A. Loginov, S. N. Ashikhmin, A. A. Fil'chikov, L. s. Shul'pina & P. V. Petrovskii

Authors
  1. A. R. Kudinov
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  2. D. A. Loginov
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  3. S. N. Ashikhmin
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  4. A. A. Fil'chikov
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  5. L. s. Shul'pina
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  6. P. V. Petrovskii
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Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1647–1649, September, 2000.

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Kudinov, A.R., Loginov, D.A., Ashikhmin, S.N. et al. Synthesis of triple-decker iron and cobalt complexes with a central tetramethylphospholyl ligand. Russ Chem Bull 49, 1637–1639 (2000). https://doi.org/10.1007/BF02495173

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  • DOI: https://doi.org/10.1007/BF02495173

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