Abstract
The low-temperature interaction of sublimed layers of manganese(ii)meso-tetraphenylporphyrinate (MnTPP) with O2, which has previously been observed only in solutions and in an inert gas matrix, was found by electron absorption and IR spectroscopy. The coordination of O2 with sublimed MnTPP layers is only partially reversible. Bands that can serve as IR-spectral markers characteristic of the high-spin MnII ion in MnTPP and its axial complexes were observed.
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1551–1555, September, 2000.
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Kurtikyan, T.S., Stepanyan, T.H., Martirosyan, G.G. et al. A spectral study of the interaction of dioxygen with sublimed layers of manganese(ii)meso-tetraphenylporphyrinate. Russ Chem Bull 49, 1540–1543 (2000). https://doi.org/10.1007/BF02495157
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DOI: https://doi.org/10.1007/BF02495157