Abstract
A method for the synthesis ofS-arylN,N-dialkylamidothiosulfates, a novel class of sulfenic acid derivatives, was proposed. The method is based on the reaction of arenesulfenyl chlorides withN,N-dialkylamidosulfinic acids or with secondary amines in liquid SO2 in the presence of triethylamine. In the presence of halogen-containing Lewis acids,S-arylN,N-dialkyl-amidothiosulfates add to the C=C bonds to give aryl β-haloalkyl sulfides.
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1484–1487, August, 2000.
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Zyk, N.V., Beloglazkina, E.K., Lapshina, O.A. et al. S-ArylN,N-dialkylamidothiosulfates, a novel class of sulfenic acid derivatives. Russ Chem Bull 49, 1478–1480 (2000). https://doi.org/10.1007/BF02495103
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DOI: https://doi.org/10.1007/BF02495103