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Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate

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Abstract

The reagent obtained from iodine monochloride and silver sulfate in sulfuric acid easily iodinates I-methyl-3-nitropyrazole under mild conditions to give 4-iodo or 4,5-diiodo derivatives, 1-Methyl-4-nitropyrazole was also directly iodinated with this reagent for the first time.

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References

  1. E. V. Tretyakov and S. F. Vasilevsky,Mendeleev Commun. 1995, 233.

  2. E. V. Tretyakov and S. F. Vasilevsky,Izv. Akad. Nauk. Ser. Khim., 1996, 2722 [Russ. Chem. Bull., 1996,45, 2581 (Engl. Transl.)].

    Google Scholar 

  3. S. F. Vasilevsky, T. V. Anisimova, and M. S. Shvartsberg,Izv. Akad. Nauk SSSR, Ser. Khim., 1983, 688 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1983,32, 626 (Engl. Transl.)].

    Google Scholar 

  4. S. F. Vasilevsky and E. V. Tretyakov,Liebigs Ann. Chem., 1995, 775.

  5. E. V. Tretyakov and S. F. Vasilevsky,Heterocycl. Commun., 1998, 519.

  6. J. H. Boer, inOrganic Nitro Chemistry. Nitroazoles. The C-Nitro Derivatives of Five-Membered N- and N,O-Heterocycles, VCH, Deerfield Beach, 1986, 186.

    Google Scholar 

  7. S. F., Vasilevsky, A. I. Belov, and M. S. Shvartsberg,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk [Bulletin of the Siberian Division of the Russian Academy of Sciences, Section of Chemical Sciences], 1985, 100 (in Russian).

  8. V. K. Chaikovski, T. S. Kharlova, V. D. Filimonov, and T. A. Saryucheva,Synthesis, 1999, 748.

  9. V. K. Chaikovskii, T. S. Kharlova, and V. D. Filimonov,Izv. Akad. Nauk, Ser. Khim., 1999, 1303 [Russ. Chem. Bull., 1999,48, 1291 (Engl. Transl.)].

    Google Scholar 

  10. S. F. Vasilevsky and M. S. Shvartsberg,Izv. Akad. Nauk SSSR, Ser. Khim., 1980, 1071 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1980,29, 778 (Engl. Transl.)].

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Authors and Affiliations

  1. Tomsk Polytechnical University, 30 prosp. Lenina, 634004, Tomsk, Russian Federation

    V. K. Chaikovskii, T. S. Kharlova & V. D. Filimonov

  2. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    E. V. Tretyakov & S. F. Vasilevsky

Authors
  1. V. K. Chaikovskii
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  2. T. S. Kharlova
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  3. E. V. Tretyakov
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  4. S. F. Vasilevsky
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  5. V. D. Filimonov
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Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1482–1484, August, 2000.

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Chaikovskii, V.K., Kharlova, T.S., Tretyakov, E.V. et al. Direct iodination of 3- and 4-nitropyrazoles with a reagent based on iodine monochloride and silver sulfate. Russ Chem Bull 49, 1475–1477 (2000). https://doi.org/10.1007/BF02495102

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  • DOI: https://doi.org/10.1007/BF02495102

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