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The reaction ofC-phenylcalix[4]resorcinarene-based polymer with quaternary ammonium and potassium cations

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Abstract

The resol polycondensation ofC-phenylcalix[4]resorcinarene with formaldehyde affords a corss-linked polymer possessing ion-exchange ability. The ion-exchange capacity of the polymer with respect to NH4 +, Me4N+, Et4N+, Bu4N+, and K+ cations was determined. The equilibrium in the systemsC-phenylcalix[4]resorcinarene-based polymer—binary or ternary aqueous solutions of electrolytes was studied by potentiometric titration and quantumchemical MNDO/PM3 calculation

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Authors and Affiliations

  1. Institute of Coal and Coal Chemistry, Siberian Branch of the Russian Academy of Sciences, 18 Sovetsky prosp, 650099, Kemerovo, Russian Federation

    G. N. Al'tshuler, O. N. Fedyaeva & E. V. Ostapova

Authors
  1. G. N. Al'tshuler
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  2. O. N. Fedyaeva
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  3. E. V. Ostapova
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1475–1477, August, 2000.

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Al'tshuler, G.N., Fedyaeva, O.N. & Ostapova, E.V. The reaction ofC-phenylcalix[4]resorcinarene-based polymer with quaternary ammonium and potassium cations. Russ Chem Bull 49, 1468–1470 (2000). https://doi.org/10.1007/BF02495099

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  • DOI: https://doi.org/10.1007/BF02495099

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