Skip to main content
SpringerLink
Log in

Study of reactions of some halides, cyclopentadienyl dichlorides, and bis(cyclopentadienyl) chlorides of lanthanides withtrans-stilbene adducts with alkali metals [PhCHCHPh]·−M+ (M=Li, Na)

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Reaction of Sml2(THF)2 with metallic lithium andtrans-stilbene in 1:2:2 ratio in DME gives the stilbene complex of divalent samarium (PhCHCHPh)Sm(DME)2. This complex reacts with hydrogen in THF to give SmH2(THF)2 and 1,2-diphenylethane. The reaction with (Me3Si)2NH gives the amide [(Me3Si)2N]2Sm(DME)2 and the reaction with triphenylgermane yields Ph3GeGePh3. Reaction of CpLuCl2(THF)2 with 2 equivalents of [PhCHCHPh]·−Na+ in DME results in the dimerization of stilbene fragments to give anate-complex {Cp2Lu[μ-CH (Ph)CH(Ph)CH(Ph)CH(Ph)]}Na(DME)3. In the reaction of Cp2GdCl with [PhCHCHPh]·−Na+, the known complex Cp3Gd(THF) was isolated as the only lanthanidecontaining product.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. B. Deacon and Q. Chen,J. Organomet. Chem., 1996,511, 1.

    Article  CAS  Google Scholar 

  2. W. J. Evans, T. A. Ulibarri, and J. W. Ziller,J. Am. Chem. Soc., 1990,112, 219.

    Article  CAS  Google Scholar 

  3. D. M. Roitershtein, J. W. Ziller, and W. J. Evans,J. Am. Chem. Soc., 1998,120, 11342.

    Article  CAS  Google Scholar 

  4. A. A. Trifonov, E. N. Kirillov, E. A. Fedorova, N. P. Makarenko, M. N. Bochkarev, H. Schumann, and S. Muehle,Izv. Akad. Nauk, Ser. Khim., 1998, 2345 [Russ. Chem. Bull., 1998,47, 2274 (Engl. Transl.)].

    Google Scholar 

  5. W. J. Evans and M. A. Hozbor,J. Organomet. Chem., 1987,326, 299.

    Article  CAS  Google Scholar 

  6. E. A. Fedorova, A. A. Trifonov, E. N. Kirillov, and M. N. Bochkarev,Izv. Akad. Nauk. Ser. Khim., 2000, 947 [Russ. Chem. Bull., Int. Ed., 2000,49, 946 (Engl. Transl.)].

    Google Scholar 

  7. Yu. F. Rad'kov, E. A. Fedorova, S. Ya. Khorshev, G. S. Kalinina, M. N. Bochkarev, and G. A. Razuvaev,Zh. Obshch. Khim., 1985,55, 2153 [J. Gen. Chem. USSR, 1985,55 (Engl. Transl.)].

    Google Scholar 

  8. E. A. Fedorova, A. A. Trifonov, M. N. Bochkarev, F. Girgsdies, and H. Schumann,Z. Anorg. Allg. Chem., 1999,625, 1.

    Article  Google Scholar 

  9. M. N. Bochkarev, I. M. Penyagina, L. N. Zakharov, Yu. F. Rad'kov, E. A. Fedorova, and Yu. T. Struchkov,J. Organomet. Chem., 1989,378, 362.

    Article  Google Scholar 

  10. A. A. Trifonov, L. N. Zakharov, M. N. Bochkarev, and Yu. T. Struchkov,Izv. Akad. Nauk, Ser. Khim., 1994, 148 [Russ. Chem. Bull., 1994,43, 145 (Engl. Transl.)].

    Google Scholar 

  11. A. A. Trifonov, P. Van de Wegh, J. Collin, A. Domingos, and I. Santos,J. Organomet. Chem., 1997,527, 225.

    Article  CAS  Google Scholar 

  12. M. N. Bochkarev, A. V. Protchenko, L. N. Zakharov, G. K. Fukin, and Yu. T. Struchkov,J. Organomet. Chem., 1995,501, 123.

    Article  CAS  Google Scholar 

  13. A. V. Protchenko and M. N. Bochkarev,Pribory i Tekhnika Eksperimenta [Experimental Equipment and Procedures], 1990,1, 194 (in Russian).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation

    A. A. Trifonov, E. A. Fedorova, E. N. Kirillov & M. N. Bochkarev

  2. Institut für anorganische und analitische Chemie, Technische Universität Berlin, 17 Juni Str. 135, D-10623, Berlin 12, Germany

    F. Girgsdies & H. Schumann

Authors
  1. A. A. Trifonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Fedorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. N. Kirillov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. N. Bochkarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. Girgsdies
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. H. Schumann
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1442–1446, August, 2000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Trifonov, A.A., Fedorova, E.A., Kirillov, E.N. et al. Study of reactions of some halides, cyclopentadienyl dichlorides, and bis(cyclopentadienyl) chlorides of lanthanides withtrans-stilbene adducts with alkali metals [PhCHCHPh]·−M+ (M=Li, Na). Russ Chem Bull 49, 1436–1439 (2000). https://doi.org/10.1007/BF02495093

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02495093

Key words

Search

Navigation