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Synthesis of difunctional organooxasilacycloalkanes

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

2,8-Dichloro-2,4,4,6,6,8,10,10,12,12-decamethyl-5-carbacyclohexasiloxane, 4,7-dichloro-2,2,4,7-tetramethyl-1,3-dioxa-2,4,7-trisilacyclohepatane, and 4,8-dichloro-2, 2,4,8-tetramethyl-1,3-dioxa-2,4,8-trisilacyclooctane were prepared for the first time by heterofunctional condensation of 1,1,7,7-tetrachloro-1,3,3,5,5,7-hexamethyl-4-carbatetrasiloxane with 1,3-dihydroxy-1,1,3,3-tetramethyldisiloxane, of 2,2,5,5-tetrachloro-2,5-disilahexane with dihydroxydimethylsilane, and of 2,2,6,6-tetrachloro-2,6-disilaheptane with dihydroxydimethylsilane, respectively. Hydrolysis of the resulting compounds afforded the corresponding dihydroxy derivatives, andtrans-isomers of some of these derivatives were isolated in individual form.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    N. V. Chizhova, T. V. Astapova, P. V. Petrovskii & N. N. Makarova

Authors
  1. N. V. Chizhova
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  2. T. V. Astapova
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  3. P. V. Petrovskii
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  4. N. N. Makarova
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1436–1441, August, 2000.

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Chizhova, N.V., Astapova, T.V., Petrovskii, P.V. et al. Synthesis of difunctional organooxasilacycloalkanes. Russ Chem Bull 49, 1430–1435 (2000). https://doi.org/10.1007/BF02495092

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  • DOI: https://doi.org/10.1007/BF02495092

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