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Temperature hysteresis phenomena in heterogeneous catalysis

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Temperature hysteresis is observed only in exothermic heterogeneous catalytic reactions (viz., oxidation and methanation of CO or propene hydrogenation) and is absent in the case of endothermic reactions (dehydrogenation of isobutane) or reactions with heat close to zero (viz., 2-butene isomerization). Temperature hysteresis in hydrogenation reactions was discovered for the first time. The concept of local overheating of catalyst active sites caused by poor removal of the reaction heat is proposed to provide a noncontradictory interpretation of the appearance of hysteresis loops.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    A. N. Subbotin, B. S. Gudkov & V. I. Yakerson

Authors
  1. A. N. Subbotin
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  2. B. S. Gudkov
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  3. V. I. Yakerson
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1379–1385, August, 2000.

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Subbotin, A.N., Gudkov, B.S. & Yakerson, V.I. Temperature hysteresis phenomena in heterogeneous catalysis. Russ Chem Bull 49, 1373–1379 (2000). https://doi.org/10.1007/BF02495080

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  • DOI: https://doi.org/10.1007/BF02495080

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