Abstract
The catalytic effect of the sodium dodecyl sulfate-hexanol-water ternary reverse micellar system in the alkaline hydrolysis ofO-alkylO′-aryl chloromethylphosphonates as a function of the substrate structure was studied. The micellar effect is mainly determined by a change in the electronic properties of the substituents, while the hydrophobicity plays a secondary role. The kinetic data were examined in the framework of the pseudo-phase model of micellar catalysis. The rate constants of the reaction in the surface layer and the partition constants of the reactants were calculated.
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1366–1370., August, 2000.
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Zakharova, L.Y., Valeeva, F.G., Shagidullina, R.A. et al. The influence of the structure of tetracoordinate phosphorus acid esters on the catalytic effect of the sodium dodecyl sulfate-hexanol-water ternary reverse micellar system. Russ Chem Bull 49, 1360–1364 (2000). https://doi.org/10.1007/BF02495077
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DOI: https://doi.org/10.1007/BF02495077